Benzoic acid–2,2′-biimidazole (2/1)

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Benzoic acid–2,2′-biimidazole (2/1)

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Diazido­bis(2,2′-biimidazole)cobalt(II)

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Diazido­bis(2,2′-biimidazole)iron(II)

In the title compound, [Fe(N(3))(2)(C(6)H(6)N(4))(2)], the Fe atom is bonded to two azide ions located in axial positions and to two equatorially positioned bidentate biimidazole ligands, forming a slightly distorterd octa-hedron. The non-H atoms of the equatorial plane are coplanar, with a mean deviation of 0.0355 (2) Å. The Fe(II) cation lies on an inversion centre. Thus, the asymmetric unit ...

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Diazido­bis(2,2′-biimidazole)manganese(II)

In the title compound, [Mn(N(3))(2)(C(6)H(6)N(4))(2)], the Mn atom (site symmetry ) is bonded to two azide ions and two bidentate biimidizole ligands, resulting in a slightly distorted octa-hedral MnN(6) geometry for the metal ion. In the crystal structure, N-H⋯N hydrogen bonds help to consolidate the packing.

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2,2′-(2,2′-Biimidazole-1,1′-di­yl)diethanoic acid

In the title compound, C(10)H(10)N(4)O(4), the two imidazole rings adopt a trans conformation and are inclined to one another at a dihedral angle of 55.64 (4)°. In the crystal structure, mol-ecules are linked by inter-molecular O-H⋯N hydrogen bonds into chains running parallel to [010] and layers are formed from these by inter-molecular C-H⋯O hydrogen bonds. Additional C-H⋯O hydrogen bonds prod...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2010

ISSN: 1600-5368

DOI: 10.1107/s1600536810045368